column 7 of the hazardous materials table column 7 of the hazardous materials table

B3 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks and DOT 57 portable tanks are not authorized. Each empty bottle must have a minimum weight of not less than 140 grams and a minimum wall thickness of not less than 0.020 inch (0.508 mm). TP22 Lubricants for portable tank fittings (for example, gaskets, shut-off valves, flanges) must be oxygen compatible. The Associate Administrator will base the authorization on results from Series 2 tests and a Series 6(c) test from the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) on packages as prepared for transport in accordance with the requirements of this subchapter. 353 Ammonium permanganate, ammonium permanganate aqueous solutions, and mixtures of a permanganate with an ammonium salt are forbidden for transport. During the course of transportation, these substances must be shaded from direct sunlight and all sources of heat and be placed in adequately ventilated areas. B133 Hydrochloric acid concentration not exceeding 38%, in Packing Group II, is authorized to be packaged in UN31H1 or UN31HH1 intermediate bulk containers when loaded in accordance with the requirements of 173.35(h) of this subchapter. For a battery whose voltage (electrical potential) exceeds 9 volts -, (1) When contained in a device, the device must be packaged in a manner that prevents unintentional activation or must have an independent means of preventing unintentional activation (e.g., packaging restricts access to activation switch, switch caps or locks, recessed switches, trigger locks, temperature sensitive circuit breakers, etc. in such a manner as to prevent short circuits, accidental operation, and significant movement relative to the cargo transport unit under the shocks, loadings, and vibrations normally incident to transport. Size of marking on bulk package must conform to 172.302(b) of this subchapter. However this examination is required when the conditions of 180.605(f) are met. N90 Metal packagings are not authorized. A lighter refill exceeding 4 fluid ounces capacity (7.22 cubic inches) or containing more than 65 grams of fuel must be classed as a Division 2.1 material, described with the proper shipping name appropriate for the material, and packaged in the packaging specified in part 173 of this subchapter for the flammable gas contained therein. If a package contains both lithium metal batteries and lithium ion batteries packed with and contained in equipment, then the shipping paper must indicate both UN 3091 Lithium metal batteries packed with equipment and UN 3481 Lithium ion batteries packed with equipment.. The manufacturer must apply procedures to ensure that articles produced in series are made of good quality, conform to the design type and are able to meet the requirements in (a). 441 For marine pollutants transported under UN3077, Environmentally hazardous substance, solid, n.o.s. or UN3082, Environmentally hazardous substance, liquid, n.o.s. and for purposes of shipping paper and package marking requirements, the technical name used in association with the basic description may be a proper shipping name listed in the 172.101 Hazardous Material Table; provided that the name chosen is not also an entry that includes n.o.s. as a part of the name or one that has a G in column (1) of the table. (a) The Hazardous Materials Table . 49 Mixtures of solids that are not subject to this subchapter and corrosive liquids may be transported under this entry without first applying the classification criteria of Class 8, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. 430 This entry shall only be used for solid medical waste of Category A transported for disposal. 139 Use of the special arrangement proper shipping names for international shipments must be made under an IAEA Certificate of Competent Authority issued by the Associate Administrator in accordance with the requirements in 173.471, 173.472, or 173.473 of this subchapter. Examples of equipment are lawnmowers, cleaning machines, or model boats and model aircraft. Model rocket motors containing 30 grams or less propellant are classed as Division 1.4S and items containing more than 30 grams of propellant but not more than 62.5 grams of propellant are classed as Division 1.4C. Date of the visual inspection must be stenciled on the tank near the other required markings. b. These provisions are multi-modal and apply to bulk and non-bulk packagings: 1 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone A (see 173.116(a) or 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. 4 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone D (see 173.116(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. b. TP6 The tank must be equipped with a pressure release device which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous material to be transported. 49 CFR 172.101 Lading in unlined tanks must be inhibited so that the corrosive effect on steel is not greater than that of hydrofluoric acid of 65 percent concentration. guide. This entry does not apply to capacitors that by design maintain a terminal voltage (e.g., asymmetrical capacitors.). Net weight of contents in wooden boxes, barrels or kegs may not exceed 45 kg (99 pounds). Table I - Maximum Ambient Temperature - Gasoline. TP12 This material is considered highly corrosive to steel. A 25 mm (1 inch) woven lining of asbestos or other approved material must be placed between the bolster slabbing and the bottom of the tank. 382 Packages containing toy plastic or paper caps for toy pistols described as UN0349, Articles, explosive, n.o.s. (6) A code containing the letter R refers to a special provision which applies only to transportation by rail. 368 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN3507 or UN2978. c. The completed package must meet the Packing Group II performance level, as applicable for combination packagings with a plastic box outer packaging, in accordance with subpart M of part 178 of this subchapter. This molecular arrangement is exactly the same as that for dithioketo QA [5]. A189 Except where the defining criteria of another class or division are met, concentrations of formaldehyde solution: a. The outside of each package must be plainly marked ARTICLES, EXPLOSIVES, N.O.S. 137 Cotton, dry; flax, dry; sisal, dry; and tampico fiber, dry are not subject to the requirements of this subchapter when they are baled in accordance with ISO 8115, Cotton Bales - Dimensions and Density (IBR, see 171.7 of this subchapter) to a density of not less than 360 kg/m3 (22.1 lb/ft3) for cotton, 400 kg/m3 (24.97 lb/ft3) for flax, 620 kg/m3 (38.71 lb/ft3) for sisal and 360 kg/m3 (22.1 lb/ft3) for tampico fiber and transported in a freight container or closed transport vehicle. Transport vehicles must be vented to prevent accumulation of vapors at a poisonous or flammable concentration. 28 The dihydrated sodium salt of dichloroisocyanuric acid does not meet the criteria for inclusion in Division 5.1 (Oxidizer) and is not subject to the requirements of this subchapter unless meeting the criteria for inclusion in another class or division. Terminal protection methods include but are not limited to the following: (i) Securely attaching covers of sufficient strength to protect the terminals; (ii) Packaging the battery in a rigid plastic packaging; or. Portable tanks containing solidified methacrylic acid must not be reheated during transportation. 49 U.S.C. N42 1A1 drums made of carbon steel with thickness of body and heads of not less than 1.3 mm (0.050 inch) and with a corrosion-resistant phenolic lining are authorized for stabilized benzyl chloride if tested and certified to the Packing Group I performance level at a specific gravity of not less than 1.8. When there is an entry in this column, refer to Section 172.102 of the federal regulations for specific information. UN2258, 1,2-Propylenediamine: In HM-260B, PHMSA removed special provision A6 from column (7) of the . View the most recent official publication: These links go to the official, published CFR, which is updated annually. 37 Unless it can be demonstrated by testing that the sensitivity of the substance in its frozen state is no greater than in its liquid state, the substance must remain liquid during normal transport conditions. A54 Irrespective of the quantity limits in Column 9B of the 172.101 table, a lithium battery, including a lithium battery packed with, or contained in, equipment that otherwise meets the applicable requirements of 173.185, may have a mass exceeding 35 kg if approved by the Associate Administrator prior to shipment. Liquefied compressed gases are assigned to portable tank instruction T50. Unfortunately, the amendments to the table entries for various hazardous materials introduced new unintended errors that PHMSA is correcting in this notice. It must not freeze at temperatures above 15 C (5 F). N84 The maximum quantity per package is 500 g (1.1 lbs.). N92 Notwithstanding the provisions of 173.24(g) of this subchapter, packagings shall be designed and constructed to permit the release of gas or vapor to prevent a build-up of pressure that could rupture the packagings in the event of loss of stabilization. Hazardous materials shipped under this entry are excepted from the labeling requirements of this subchapter unless offered for transportation or transported by aircraft and are not subject to the placarding requirements of subpart F of this part. Symbols, if used, must be registered with the Associate Administrator. B5 Only ammonium nitrate solutions with 35 percent or less water that will remain completely in solution under all conditions of transport at a maximum lading temperature of 116 C (240 F) are authorized for transport in the following bulk packagings: MC 307, MC 312, DOT 407 and DOT 412 cargo tanks with at least 172 kPa (25 psig) design pressure. N95 UN1075, Liquefied petroleum gas and UN1978, Propane authorized for transport in DOT 4BA240 cylinders is not subject to the UN identification number and proper shipping name marking or the label requirements of this part subject to the following conditions: a. metal other than steel or aluminum (50N). 50 Cases, cartridge, empty with primer which are made of metallic or plastic casings and meeting the classification criteria of Division 1.4 are not regulated for domestic transportation. Background and more details are available in the 26 This entry does not include ammonium permanganate, the transport of which is prohibited except when approved by the Associate Administrator. c. The cylinders are collected and transported by a private or a contract carrier for reconditioning, reuse or disposal. 2 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone B (see 173.116(a) or 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. Regulation Y information or personal data. B77 Other packaging are authorized when approved by the Associate Administrator. (ii) The following is a list of the portable tank special provisions: TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. Furthermore, lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit must be described using the proper shipping name Lithium batteries installed in cargo transport unit found in the 172.101 Hazardous Materials Table. 155 Fish meal, fish scrap and krill meal may not be transported if the temperature at the time of loading either exceeds 35 C (95 F), or exceeds 5 C (41 F) above the ambient temperature, whichever is higher. 45 Temperature should be maintained between 18 C (64.4 F) and 40 C (104 F). B83 Bottom outlets are prohibited on tank car tanks transporting sulfuric acid in concentrations over 65.25 percent. . 5 If this material meets the definition for a material poisonous by inhalation (see 171.8 of this subchapter), a shipping name must be selected which identifies the inhalation hazard, in Division 2.3 or Division 6.1, as appropriate. (eg: Title 49 was last amended 2/03/2023. The means of protection must be approved by the approval agency designated to approve the portable tank in accordance with the procedures in part 107, subpart E, of this subchapter. For non-pressurized lighters containing a Class 3 (flammable liquid) material, its design, description, and packaging must be approved by the Associate Administrator prior to being offered for transportation or transported in commerce. However, button cell batteries installed in equipment (including circuit boards) need not be considered; and, c. The shipping paper must indicate UN 3091 Lithium metal batteries packed with equipment or UN 3481 Lithium ion batteries packed with equipment, as appropriate. shipping name in Column (1) of the 172.101 Table, it means that the mate-rial is known to pose a risk to humans. B52 Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief devices are authorized on DOT 57 portable tanks. (6) R codes. 24 Alcoholic beverages containing more than 70 percent alcohol by volume must be transported as materials in Packing Group II. Single unit tank car tanks must have a reclosing pressure relief device having a start-to-discharge pressure set at no more than 1551 kPa (225 psig). b. (2) An indication of compliance with this special provision must be provided by marking each package with the words not restricted or by including the words not restricted on a transport document such as an air waybill accompanying the shipment. Outage must be sufficient to prevent tanks from becoming liquid full at 55 C (130 F). Except for transportation by aircraft, in palletized loads, a pallet box or unit load device (e.g. Only Specifications MC 304, MC 307 or DOT 407 cargo tank motor vehicles are authorized for transportation by vessel. The present arrangement occurs in such a way that one QA molecule is hydrogen-bonded to four neighboring molecules: two different molecules in one column and other two molecules in another column. 175 This substance must be stabilized when in concentrations of not more than 99%. f. Flexible: 13H2, 13H3, 13H4, 13H5, 13L2, 13L3, 13L4, 13M1 and 13M2 (flexible IBCs must be sift-proof and water resistant or must be fitted with a sift-proof and water resistant liner). a. The material is also be subject to operational controls which include not exceeding a temperature of 55C (130F) at the time it is offered or during transportation, not exceeding a transportation time of 24 hours, and drivers transporting spent bleaching earth must be trained in the properties and hazards of the spent bleaching earth. 102 The ends of the detonating cord must be tied fast so that the explosive cannot escape. 53 Packages of these materials must bear the subsidiary risk label, EXPLOSIVE, and the subsidiary hazard class/division must be entered in parentheses immediately following the primary hazard class in the shipping description, unless otherwise provided in this subchapter or through an approval issued by the Associate Administrator, or the competent authority of the country of origin. B44 All parts of valves and safety relief devices in contact with lading must be of a material which will not cause formation of acetylides. 30 Sulfur is not subject to the requirements of this subchapter if transported in a non-bulk packaging or if formed to a specific shape (for example, prills, granules, pellets, pastilles, or flakes). For the purpose of this special provision, vehicles are self-propelled apparatus designed to carry one or more persons or goods. A13 Bulk packagings are not authorized for transportation by aircraft. A34 Aerosols containing a corrosive liquid in Packing Group II charged with a gas are not permitted for transportation by aircraft. Uranium hexafluoride may be classified under this entry only if the conditions of 173.420(a)(4) and (6) and (d) and 173.421(b) and (d) of this subchapter, and, for fissile-excepted material, the conditions of 173.453 of this subchapter are met. N91 The use of a non specification sift-proof, non-bulk, metal can with or without lid, or a non specification sift-proof, non-bulk fiber drum, with or without lid is authorized when transporting coal tar pitch compounds by motor vehicle or rail freight. The chemical under pressure must be classed based on the hazard characteristics of the components in the propellant; the liquid; or the solid. Table 1. B15 Packagings must be protected with non-metallic linings impervious to the lading or have a suitable corrosion allowance. This provision may be used for both domestic and international shipments. This entry also applies to articles not conforming to the requirements of 173.302, 173.304, or 173.306 of this subchapter, containing a small pressure receptacle with a release device. A combination packaging consisting of a 4G fiberboard box with inner receptacles of glass or earthenware; b. The provisions of this special provision will be effective until January 2, 2023, unless we terminate them earlier or extend them beyond that date by notice of a final rule in the Federal Register. The rechargeable (and some non-rechargeable) types have gelled alkaline electrolytes (rather than acidic) making it difficult for them to generate hydrogen or oxygen when overcharged and therefore, differentiating them from non-spillable batteries. An important, but often overlooked, requirement for the safe and regulatory compliant transportation of a HazMat is an understanding of the special provisions in column 7 of the Hazardous Materials Table. TP40 The portable tank must not be transported when connected with spray application equipment. Except as otherwise provided in this subchapter, these special provisions do not apply to UN portable tanks or IBCs: B1 If the material has a flash point at or above 38 C (100 F) and below 93 C (200 F), then the bulk packaging requirements of 173.241 of this subchapter are applicable. 144 If transported as a residue in an underground storage tank (UST), as defined in 40 CFR 280.12, that has been cleaned and purged or rendered inert according to the American Petroleum Institute (API) Standard 1604 (IBR, see 171.7 of this subchapter), then the tank and this material are not subject to any other requirements of this subchapter. Example: Yes, I would like to receive emails from Daniels Training Services. (iii) A copy of the test results must be kept on file at each facility where packagings are offered for transportation, and must be made available to a representative of the Department upon request. Lead compounds which, when mixed in a ratio of 1:1,000 with 0.07 M (Molar concentration) hydrochloric acid and stirred for one hour at a temperature of 23 C 2 C, exhibit a solubility of 5% or less are not subject to the requirements of this subchapter unless they meet criteria as another hazard class or division. Batteries contained in devices must be securely installed. (2) A codes. Where the quantity of hazardous materials contained as an integral element in machinery or apparatus exceeds the limits permitted by 173.222(c)(2), and the hazardous materials meet the provisions of 173.222(c), the machinery or apparatus may be transported by aircraft only with the prior approval of the Associate Administrator. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. B4 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized. Each special provision is indicated using a numeric or alphanumeric code. B90 Steel tanks conforming or equivalent to ASME specifications which contain solid or semisolid residual motor fuel antiknock mixture (including rust, scale, or other contaminants) may be shipped by rail freight or highway. (3) A flammable gas is a gas that meets the criteria in 173.115 of this subchapter. The packaging shall be designed for a working temperature of at least 121 C (250 F). These requirements must be met in addition to the design and construction specifications in part 178 of this subchapter. In addition, the portable tank must be designed so that internal surfaces may be effectively cleaned and passivated. The adsorbent or absorbent material shall not meet the definition or criteria for inclusion in Classes 1 to 8; c. The maximum contents of a receptacle shall be 10 kg of ammonia; and. This entry does not apply to life saving appliances described in 173.219 (UN2990 and UN3072). Column 7 of the 172.101 Hazmat Table lists the special provisions that apply to an individual proper shipping name. For other than Class 7 or the DANGEROUS . This may be fulfilled by an additional locking device linked to the activator; (4) Each article must be manufactured in such a way as to prevent hazardous projections of the pressure receptacle or parts of the pressure receptacle; (5) Each pressure receptacle must be manufactured from material which will not fragment upon rupture; (6) The design type of the article must be subjected to a fire test. The official, published CFR, is updated annually and available below under The quantities of hazardous materials do not exceed those specified in 173.4a of this subchapter; and. 64 The group of alkali metals includes lithium, sodium, potassium, rubidium, and caesium. When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. 369 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN 2978. 237 Batteries, dry, containing potassium hydroxide solid, electric storage must be prepared and packaged in accordance with the requirements of 173.159(a) and (c). TP20 This hazardous material must only be transported in insulated tanks under a nitrogen blanket. Capacitors with an energy storage capacity of 0.3 Wh or less are not subject to the requirements of this subchapter. Use of these proper shipping names for domestic shipments may be made only under a DOT special permit, as defined in, and in accordance with the requirements of subpart B of part 107 of this subchapter. With less than 10 percent formaldehyde, are not subject to this subchapter. B136 Non-specification closed bulk bins are authorized. 110 Fire extinguishers transported under UN1044 and oxygen cylinders transported for emergency use under UN1072 may include installed actuating cartridges (cartridges, power device of Division 1.4C or 1.4S), without changing the classification of Division 2.2, provided the aggregate quantity of deflagrating (propellant) explosives does not exceed 3.2 grams per cylinder. When a special provision specifies packaging or packaging requirements - There you have it! d. In addition to the training requirements prescribed in 172.700 through 172.704, each driver must be trained regarding the properties and hazards of diatomaceous earth filter material, precautions to ensure safe transport of the material, and actions to be taken in the event of an emergency during transportation, or a substantial delay in transit. 380 For transportation by private carrier in a motor carrier only, this material is not subject to the segregation requirements of 177.848(d) of this subchapter under the following conditions: a. 105 The word Agents may be used instead of Explosives when approved by the Associate Administrator. Specifically, you seek clarification on the implementation of special provision IP15which is listed in Column 7 of the 172.101 Hazardous Materials Table (HMT)as it applies when this material is packaged in a composite intermediate bulk container (IBC) with a rigid inner receptacle. For UN 3176, this requirement only applies when the hazardous material reacts dangerously with water. Such articles must comply with the following requirements: (1) The water capacity of the pressure receptacle must not exceed 0.5 L and the working pressure must not exceed 25 bar at 15 C (59 F); (2) The minimum burst pressure of the pressure receptacle must be at least four times the pressure of the gas at 15 C (59 F); (3) Each article must be manufactured in such a way that unintentional firing or release is avoided under normal conditions of handling, packing, transport and use. In addition, for solid materials, special provision B54 applies. 166 When transported in non-friable tablet form, calcium hypochlorite, dry, may be transported as a Packing Group III material. In addition, a container exceeding 4 fluid ounces volumetric capacity (7.22 cubic inches) or containing more than 65 grams of fuel may not be connected or manifolded to a lighter or similar device and must also be described and packaged according to the fuel contained therein. Special provisions contain packaging provisions, prohibitions, exceptions from requirements for particular quantities or forms of materials and requirements or prohibitions applicable to specific modes of transportation, as follows: (1) A code consisting only of numbers (for example, 11) is multi-modal in application and may apply to bulk and non-bulk packagings. If you have comments or suggestions on how to improve the www.ecfr.gov website or have questions about using www.ecfr.gov, please choose the 'Website Feedback' button below. N4 For combination or composite packagings, glass inner packagings, other than ampoules, are not permitted. Primary receptacles must conform to the general packaging requirements of subpart B of part 173 of this subchapter and may not leak. Based on the volatility class determined by using ASTM D 439 and the Reid vapor pressure (RVP) of the particular gasoline, the maximum lading pressure and maximum ambient temperature permitted during the loading of gasoline may not exceed that listed in Table I. B85 Cargo tanks must be marked with the name of the lading in accordance with the requirements of 172.302(b). If a fuel cell engine is installed in a vehicle, the vehicle must be described using Vehicle, fuel cell, flammable gas powered or Vehicle, fuel cell, flammable liquid powered, as appropriate. (3) The total amount of gas from all detectors per outer packaging must not exceed 52 grams (1.83 ounces). All openings must be closed with gasketed blank flanges or vapor tight threaded closures. B30 MC 312, MC 330, MC 331 and DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. 81 Polychlorinated biphenyl items, as defined in 40 CFR 761.3, for which specification packagings are impractical, may be packaged in non-specification packagings meeting the general packaging requirements of subparts A and B of part 173 of this subchapter. The article, machinery, or apparatus, if unpackaged, or the packaging in which it is contained shall be marked Dangerous goods in articles or Dangerous goods in machinery or Dangerous goods in apparatus as appropriate, with the identification number UN3363. Additionally, each cylinder must be visually inspected in accordance with CGA pamphlet, CGA C-6 (incorporated by reference, see 171.7). A10 When aluminum or aluminum alloy construction materials are used, they must be resistant to corrosion. A3 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with absorbent material in tightly closed rigid and leakproof receptacles before packing in outer packagings.